Green Chemistry Principles In Biopolymer Synthesis

Authors

  • Kenjayeva Nargiza Razzaqovna Teacher, Department of Medical and Biological Chemistry, Bukhara State Medical Institute, Uzbekistan

Keywords:

Green chemistry, biopolymers, polylactic acid (PLA)

Abstract

The transition to sustainable polymer production is urgent in response to global plastic pollution and fossil resource depletion. Biopolymers — derived from renewable resources or produced biologically — offer promising alternatives to conventional plastics, but their synthesis and processing must adhere to green chemistry principles to realize environmental benefits. This review synthesizes core green chemistry strategies applied in biopolymer synthesis, including renewable feedstocks, benign solvents, enzyme and heterogeneous catalysis, energy-efficient processes, and waste-minimization. Case studies on polylactic acid (PLA), chitosan, and bacterial cellulose illustrate practical implementations and techno-economic considerations. Metrics and life cycle assessment (LCA) approaches used to quantify “greenness” are discussed, as are challenges for scale-up and regulatory acceptance. Recommendations highlight integrated process design, circularity through end-of-life planning, and interdisciplinary research needs to accelerate adoption.

The transition to sustainable polymer production is urgent in response to global plastic pollution and fossil resource depletion. Biopolymers — derived from renewable resources or produced biologically — offer promising alternatives to conventional plastics, but their synthesis and processing must adhere to green chemistry principles to realize environmental benefits. This review synthesizes core green chemistry strategies applied in biopolymer synthesis, including renewable feedstocks, benign solvents, enzyme and heterogeneous catalysis, energy-efficient processes, and waste-minimization. Case studies on polylactic acid (PLA), chitosan, and bacterial cellulose illustrate practical implementations and techno-economic considerations. Metrics and life cycle assessment (LCA) approaches used to quantify “greenness” are discussed, as are challenges for scale-up and regulatory acceptance. Recommendations highlight integrated process design, circularity through end-of-life planning, and interdisciplinary research needs to accelerate adoption.

References

Kerton, F. M. (2024). Applying the principles of green chemistry to achieve a more sustainable polymer economy. (Mini-review).

Khouri, N. G., et al. (2024). Polylactic acid (PLA): Properties, synthesis, and biomedical applications. Comprehensive review on PLA production and applications.

Mohan, K., et al. (2022). Green and eco-friendly approaches for the extraction of chitin and chitosan. Reviews green extraction techniques for chitin/chitosan.

Mersmann, L., et al. (2025). Green Processes for Chitin and Chitosan Production from Insect and Marine Sources. Critical review of emerging greener approaches.

El-Gendi, H., et al. (2022). Recent advances in bacterial cellulose: a low-cost effective production and application perspective. Discusses use of agro/industrial wastes as BC media.

Poddar, M. K., et al. (2021). Recent development in bacterial cellulose production and applications. Review on BC production and composites.

Ali, W., et al. (2023). Polylactic acid: synthesis, biodegradability, conversion to microplastics, and environmental impact. LCA-focused review of PLA.

Khikani, M., et al. (2024). Green synthesis of nanoparticle-loaded bacterial cellulose composites. Example of green functionalization methods.

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Published

2025-11-10